Hi Bradleyz,
Standard deviation will be a measure of risk when you view an asset in isolation. Beta will be the measure of risk of an asset for a well diversified portfolio.
IMHO, it is not true that standard deviation = beta + unsystematic risk
The reason is that beta is the slope of the line of best fit when you regress asset return on an index return. Since beta is a slope, it does not have any unit, it is only a number. Beta tells you whether the asset is more or less volatile than the index and standard deviation tells you how spread out the return for the asset is.
Whenever you do any regression with only one independent variable (as will be the case for this beta computation), the distance between any single return and the line of best fit will be an error term, or in this case, unsystematic risk. Note that in order to do this linear regression you need values for both the dependent and independent variable. In order to compute a standard deviation, you need returns only for that one asset (and no index, for example).
Both standard deviation and beta are measures of risk but they cannot be added or subtracted from each other.