There may be number of portfolios that may give bigger return than market portfolio. However, we have to ask the question at what cost(risk). Considering standard deviation of returns as risk, sharpe ratio gives the excess return per unit of additional risk.
For example you have 4% return on risk free asset and 10% return on market portfolio (A theoretical portfolio with all different classes of asset available for investing across the globe) and with the assumption of perfect markets and risk/return based investor expectations, all the systematic risk is diversified and only risk left is unsystematic risk due to business cycles. So this portfolio gives the best return per additional unit of risk taken. Any other portfolio, irrespective of there returns (high/low), return per unit of risk taken (sharpe ratio) is less than that of market portfolio.
Now with this combination of risk free asset and market portfolio taking additional risk, i.e., using leverage (borrowing at risk free rate) and investing in market portfolio you can generate any rate of returns. You can double or triple your returns.
The CAPM evaluates every asset with two assets, 1. risk free asset and 2. market portfolio (theoretically the best portfolio that contains all risky assets in the world in a combination that gives highest return for every unit of risk taken, sharpe ratio).
Now if you consider S&P as market portfolio with 500 assets (not perfect, relaxing assumptions) with certain return and risk, you get SML. You could build a portfolio with 40 assets with the same return and risk characteristics or may be 50 assets or so on … infinite # of combinations of assets and weights. SML plots above CML because SML is theoretical perfect portfolio, so in theory all systematic risk is not diversified, so it must return higher rate than CML.
Relaxing the assumptions further if you find set of assets that are undervalued you could build a portfolio with those under valued assets and generate alpha. Eventually your portfolio line will be above CML and SML. This way you can have infinite # lines with portfolios with combination of different assets with different weights.
A portfolio is simply a combination of risk free asset (for a high return portfolio this could be -ve, i.e., leverage) and different risk assets at certain weights. Logically speaking every asset or set of assets or portfolio or set of portfolios must return more than market portfolio, because it is exposed to non systematic risk in addition to systematic risk. Now if it does not then we say this portfolio lies below CML/SML and not worthy to invest in.