canbonbon, based on my experience at LI last year, it's highly unlikely you'll be given a set of data large enough to require your calculator's DATA and STAT functionality. Time is of the essence and testing your abilities at straight-up-data-entry isn't a material way to differentiate you from other candidates. It doesn't hurt to know these features of your calculator, but it won't make or break you on the exam.
The quant questions will be split between calculations and interpretations. The easy part will be memorizing all the formulas. It's imperative that you make time to understand the material properties and uses of each figure so you'll be prepared for the qualitative questions, which in all likelyhood will be phrased somewhat awkwardly.
Some things to know about your calculator in general (assumes TI BA II Plus, this list isn't exhaustive):
- use CF to calculate NPV and IRR
- use CF to solve P0 for multi-stage dividend discount model (saves a lot of time)
- use TVM to solve for equivalent annual annuity (corporate finance)
- use TVM to determine the book value of a new debt issue (FSA)
- misc features like LN, e^x, nCr, nPr, x!
Good luck on your LI exam! Just my $0.02.